A mine was started in 1692 by Sir Richard Standish in partnership with two farmers and a mining engineer and after several failures lead was extracted. In 1694 Richard Standish declared in the Chancery Court that he could not sign over the mines to his wife as he was a tenant.
After his death, his widow claimed the profits but lost the resultant court case and flooded the mines by diverting a stream. The operation restarted and was expanded and in 1788-1789, 73 tons of lead were produced. In the 1790s copper and galena were produced. Production ended in 1837 when a lease, granted by Frank Hall Standish in 1823 to the Thompsons of Wigan was relinquished and the unsuccessful enterprise was abandoned.
Lead Mines Clough had numerous shafts up to 240 feet deep and on the site was a smelting mill, a smithy and a waterwheel provided power. There are remains of bell pits at Dean Brook and spoil heaps containing traces of barites, calcite and galena. The mines were sealed in 1930 but there has been speculation that the site was part of a secret operation in 1940.
The mineral witherite (barium carbonate) was discovered in spoil from the mines in the 18th century. It was distinct from other sources as it contained above two per cent of carbonate of strontites. Up to this time witherite was considered worthless and used as rat poison by locals. Josiah Wedgwood used it to manufacture Jasper ware and tried to keep the source secret, but after a visit in 1782 by two Frenchmen, a local farmer, James Smithels, exported the mineral to Germany, charging five guineas per ton.